Graphene‐Encapsulated Co9S8 Nanoparticles on N,S‐Codoped Carbon Nanotubes: An Efficient Bifunctional Oxygen Electrocatalyst
N,S共掺杂碳纳米管上石墨烯包封的Co9S8纳米粒子:一种高效的双功能氧电催化剂
出版日期:2019
作者单位:NanJia,KeyLaboratoryofAppliedSurfaceandColloidChemistry(MinistryofEducation)ShaanxiKeyLaboratoryforAdvancedEnergyDevicesShaanxiEngineeringLabforAdvancedEnergyTechnologySchoolofMaterialsScienceandEngineeringShaanxiNormalUniversityXi'an710119P.R.China,JingLiu,KeyLaboratoryofAppliedSurfaceandColloidChemistry(MinistryofEducation)ShaanxiKeyLaboratoryforAdvancedEnergyDevicesShaanxiEngineeringLabforAdvancedEnergyTechnologySchoolofMaterialsScienceandEngineeringShaanxiNormalUniversityXi'an710119P.R.China,YunshanGao,KeyLaboratoryofAppliedSurfaceandColloidChemistry(MinistryofEducation)ShaanxiKeyLaboratoryforAdvancedEnergyDevicesShaanxiEngineeringLabforAdvancedEnergyTechnologySchoolofMaterialsScienceandEngineeringShaanxiNormalUniversityXi'an710119P.R.China,PeiChen,KeyLaboratoryofAppliedSurfaceandColloidChemistry(MinistryofEducation)ShaanxiKeyLaboratoryforAdvancedEnergyDevicesShaanxiEngineeringLabforAdvancedEnergyTechnologySchoolofMaterialsScienceandEngineeringShaanxiNormalUniversityXi'an710119P.R.China,XinbingChen,KeyLaboratoryofAppliedSurfaceandColloidChemistry(MinistryofEducation)ShaanxiKeyLaboratoryforAdvancedEnergyDevicesShaanxiEngineeringLabforAdvancedEnergyTechnologySchoolofMaterialsScienceandEngineeringShaanxiNormalUniversityXi'an710119P.R.China,ZhongweiAn,KeyLaboratoryofApp杂志名称:ChemSusChem
卷号:12
期数:14
刊号:1864-5631
出版日期:2019
简介:Aninexpensiveandefficientbifunctionalelectrocatalystfortheoxygenreductionreaction(ORR)andtheoxygenevolutionreaction(OER)iscentraltotherechargeablezinc–airbattery.Herein,ananohybrid,inwhichN,S‐codopedcarbonnanotubesweredecoratedwithCo9S8nanoparticlesencapsulatedinporousgraphenelayers,wasfabricatedbyaone‐stepheat‐treatmentprocess.TheN,SdopantspecieswerethemajoractivesitesfortheORR,andCo9S8nanoparticlesweremainlyresponsiblefortheOER.Comparedwithcommercial20?wt?%Pt/CandIr/Celectrocatalysts,thisnanohybridexhibitedacomparableORRhalf‐wavepotential(0.831?Vvs.reversiblehydrogenelectrode)andOERpotential(1.591?Vat10?mA?cm?2),betterlong‐termstabilityinanalkalinemedium,andanarrowerpotentialgap(0.76?V)betweenORRandOER.Furthermore,asairelectrodeoftherechargeablezinc–airbattery,itdeliveredalowcharge–dischargevoltagegap(0.65?Vat5?mA?cm?2),highopen‐circuitpotential(1.539?V),goodspecificcapacity(805?mA?h?gat5?mA?cm?2),andexcellentcyclingstability(48?h),superiortothoseofcommercialPt/CandIr/Ccatalysts,andthusshowedpromiseforapplicationsinrenewableenergyconversiondevices.