Crystal Structure,Luminescence,and Thermodynamic Properties of Pb<sub>10 –sub> <sub><em>xem>sub>Eu<sub><em>xem>sub>(GeO<sub>4sub>)<sub>2 +sub> <sub><em>xem>sub>(VO<sub>4sub>)<sub>4 –sub> <sub><em>xem>sub> (<em>xem> = 0.1,0.2,0.3) Substituted Apatites