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  • Highly conductive divalent fluorosulfonyl imide based electrolytes improving Li-ion battery performance: Additive potentiating electrolytes action

    高导电性二价氟磺酰亚胺基电解质改善锂离子电池性能:添加剂增强电解质作用

    1 约10页 pdf
    标签: Lithium-ion battery Imide electrolyte Additive Anodic stability Specific capacity

    出版日期:2020


    杂志名称:Journal of Power Sources
    卷号:455
    期数:Complete
    刊号:0378-7753
    出版日期:2020

    简介:Imide-basedelectrolytesaltsarecrucialinlithium-ionbattery(LIB)research,duetotheirhighoxidativecapacity,thermalperformance,andcyclingstability.LIBswithimideelectrolytesexhibitslowcharge-discharge(CD)capacityandhighefficiency,eventhoughmostoftheseelectrolytesshowlowionicconductivity(σ).Herein,wehavesynthesizedtwohighlyconductiveandpuredivalentimideelectrolytes,lithiumsulfonylbis(fluorosulfonyl)imide(LiSFSI)andlithium(1,3-phenylenedisulfonyl)bis(fluorosulfonyl)imide(LiPDSFSI),forLIBsapplication.ComparedtoLiPDSFSIelectrolyte,theLiSFSIimideelectrolytewithmixedsolventethylenecarbonate(EC)anddimethylsulfoxide(DMSO)(75:25v/v)exhibitsbetterelectrochemicalstability,σ,transferencenumber(tL+),cyclingstability,andhighspecificcapacityof142?mAhg?1withthefullcellbatteryconfigurationofLiFePO4/electrolytes/graphiteat0.1C.Additionally,lithiumbis(fluoro-sulfonyl)imide(LiFSI)(20%),asadditive,improvetheirperformancesubstantially.TheresultsdemonstratethattheLiSFSIelectrolytewithLiFSIadditiveshowsmaximumσ(8.9?mS/cmat30?°C),tLi+(0.64),andanodicstability(5.47?V),whichconcurrentlydelivershighefficiencyandimprovesspecificcapacityto156?mAhg?1withexcellentcapacityretention(99.93%)after500CDcycleswiththefullcellLiFePO4/electrolytes/graphitebatterysystem."

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